Ruthenium Element Information, Facts, Properties, Trends, Uses, Comparison with other elements
Ruthenium is a chemical element with symbol Ru and atomic number 44. It is a rare Transition Metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to most other chemicals.
It belongs to group 8 of the periodic table having trivial name null. You can also download Printable Periodic Table of Elements Flashcards for Ruthenium in a PDF format.
Ruthenium Facts
Read key information and facts about element Ruthenium
Name | Ruthenium |
Atomic Number | 44 |
Atomic Symbol | Ru |
Atomic Weight | 101.07 |
Phase | Solid |
Color | Silver |
Appearance | silvery white metallic |
Classification | Transition Metal |
Natural Occurance | Primordial |
Group in Periodic Table | 8 |
Group Name | iron family |
Period in Periodic Table | period 5 |
Block in Periodic Table | d-block |
Electronic Configuration | [Kr] 4d7 5s1 |
Electronic Shell Structure (Electrons per shell) | 2, 8, 18, 15, 1 |
Melting Point | 2607 K |
Boiling Point | 4423 K |
CAS Number | CAS7440-18-8 |
How to Locate Ruthenium on Periodic Table
Periodic table is arranged by atomic number, number of protons in the nucleus which is same as number of electrons. The atomic number increases from left to right. Periodic table starts at top left ( Atomic number 1) and ends at bottom right (atomic number 118). Therefore you can directly look for atomic number 44 to find Ruthenium on periodic table.
Another way to read periodic table and locate an element is by using group number (column) and period number (row). To locate Ruthenium on periodic table look for cross section of group 8 and period 5 in the modern periodic table.
Ruthenium History
The element Ruthenium was discovered by K. Claus in year 1844 in Russia. Ruthenium was first isolated by K. Claus in 1844. Ruthenium derived its name from Ruthenia, the New Latin name for Russia.
Discovered By | K. Claus |
Discovery Date | 1844 in Russia |
First Isolation | 1844 |
Isolated by | K. Claus |
Gottfried Wilhelm Osann thought that he found three new metals in Russian platinum samples, and in 1844 Karl Karlovich Klaus confirmed that there was a new element.
Ruthenium Uses
Ruthenium is used as a catalyst to harden metals. It is also used in electrical contacts and to color glass.
Ruthenium Presence: Abundance in Nature and Around Us
The table below shows the abundance of Ruthenium in Universe, Sun, Meteorites, Earth's Crust, Oceans and Human Body.
ppb by weight (1ppb =10^-7 %) | ppb by atoms (1ppb =10^-7 %) | |
---|---|---|
Abundance in Universe | 4 | 0.05 |
Abundance in Sun | 5 | 0.06 |
Abundance in Meteorites | 830 | 160 |
Abundance in Earth's Crust | 1.0 | 0.2 |
Abundance in Oceans | 0.0007 | 0.000043 |
Abundance in Humans | - | - |
Crystal Structure of Ruthenium
The solid state structure of Ruthenium is Simple Hexagonal.
The Crystal structure can be described in terms of its unit Cell. The unit Cells repeats itself in three dimensional space to form the structure.
Unit Cell Parameters
The unit cell is represented in terms of its lattice parameters, which are the lengths of the cell edges Lattice Constants (a, b and c)
a | b | c |
---|---|---|
270.59 pm | 270.59 pm | 428.15 pm |
and the angles between them Lattice Angles (alpha, beta and gamma).
alpha | beta | gamma |
---|---|---|
π/2 | π/2 | 2 π/3 |
The positions of the atoms inside the unit cell are described by the set of atomic positions ( xi, yi, zi) measured from a reference lattice point.
The symmetry properties of the crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space are described by the 230 space groups (219 distinct types, or 230 if chiral copies are considered distinct.
Space Group Name | P63/mmc |
Space Group Number | 194 |
Crystal Structure | Simple Hexagonal |
Number of atoms per unit cell |
The number of atoms per unit cell in a simple cubic, face-centered cubic and body-centred cubic are 1,4,2 respectively.
Ruthenium Atomic and Orbital Properties
Ruthenium atoms have 44 electrons and the electronic shell structure is [2, 8, 18, 15, 1] with Atomic Term Symbol (Quantum Numbers) 5F5.
Atomic Number | 44 |
Number of Electrons (with no charge) | 44 |
Number of Protons | 44 |
Mass Number | 101 |
Number of Neutrons | 57 |
Shell structure (Electrons per energy level) | 2, 8, 18, 15, 1 |
Electron Configuration | [Kr] 4d7 5s1 |
Valence Electrons | 4d7 5s1 |
Valence (Valency) | 6 |
Main Oxidation States | 3, 4 |
Oxidation States | -4, -2, 0, 1, 2, 3, 4, 5, 6, 7, 8 |
Atomic Term Symbol (Quantum Numbers) | 5F5 |
Bohr Atomic Model of Ruthenium - Electrons per energy level
n | s | p | d | f |
---|
Ground State Electronic Configuration of Ruthenium - neutral Ruthenium atom
Abbreviated electronic configuration of Ruthenium
The ground state abbreviated electronic configuration of Neutral Ruthenium atom is [Kr] 4d7 5s1. The portion of Ruthenium configuration that is equivalent to the noble gas of the preceding period, is abbreviated as [Kr]. For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. This is important as it is the Valence electrons 4d7 5s1, electrons in the outermost shell that determine the chemical properties of the element.
Unabbreviated electronic configuration of neutral Ruthenium
Complete ground state electronic configuration for the Ruthenium atom, Unabbreviated electronic configuration
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d7 5s1
Electrons are filled in atomic orbitals as per the order determined by the Aufbau principle, Pauli Exclusion Principle and Hund’s Rule.
As per the Aufbau principle the electrons will occupy the orbitals having lower energies before occupying higher energy orbitals. According to this principle, electrons are filled in the following order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p…
The Pauli exclusion principle states that a maximum of two electrons, each having opposite spins, can fit in an orbital.
Hund's rule states that every orbital in a given subshell is singly occupied by electrons before a second electron is filled in an orbital.
Atomic Structure of Ruthenium
Ruthenium atomic radius is 178 pm, while it's covalent radius is 126 pm.
Atomic Radius Calculated | 178 pm(1.78 Å) |
Atomic Radius Empirical | 130 pm (1.3 Å) |
Atomic Volume | 8.1706 cm3/mol |
Covalent Radius | 126 pm (1.26 Å) |
Van der Waals Radius | - |
Neutron Cross Section | 2.6 |
Neutron Mass Absorption | 0.0009 |
Spectral Lines of Ruthenium - Atomic Spectrum of Ruthenium
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from an excess or deficiency of photons in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral lines are the result of interaction between a quantum system and a single photon. A spectral line may be observed either as an emission line or an absorption line.
Spectral lines are highly atom-specific, and can be used to identify the chemical composition of any medium. Several elements, including helium, thallium, and caesium, were discovered by spectroscopic means. They are widely used to determine the physical conditions of stars and other celestial bodies that cannot be analyzed by other means.
Emission spectrum of Ruthenium
Absorption spectrum of Ruthenium
Ruthenium Chemical Properties: Ruthenium Ionization Energies and electron affinity
The electron affinity of Ruthenium is 101.3 kJ/mol.
Valence | 6 |
Electronegativity | 2.2 |
ElectronAffinity | 101.3 kJ/mol |
Ionization Energy of Ruthenium
Ionization energy is the amount of energy required to remove an electron from an atom or molecule.in chemistry, this energy is expresed in kilocalories per mole (kcal/mol) or kilojoules per mole (kJ/mol).
Refer to table below for Ionization energies of Ruthenium
Ionization energy number | Enthalpy - kJ/mol |
---|---|
1st | 710.2 |
2nd | 1620 |
3rd | 2747 |
Ruthenium Physical Properties
Refer to below table for Ruthenium Physical Properties
Density | 12.37 g/cm3(when liquid at m.p density is $10.65 g/cm3) |
Molar Volume | 8.1706 cm3/mol |
Elastic Properties
Young Modulus | 447 |
Shear Modulus | 173 GPa |
Bulk Modulus | 220 GPa |
Poisson Ratio | 0.3 |
Hardness of Ruthenium - Tests to Measure of Hardness of Element
Mohs Hardness | 6.5 MPa |
Vickers Hardness | - |
Brinell Hardness | 2160 MPa |
Ruthenium Electrical Properties
Electrical resistivity measures element's electrical resistance or how strongly it resists electric current.The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). While Electrical conductivity is the reciprocal of electrical resistivity. It represents a element's ability to conduct electric current. The SI unit of electrical conductivity is siemens per metre (S/m).
Ruthenium is a conductor of electricity. Refer to table below for the Electrical properties of Ruthenium
Electrical conductors | Conductor |
Electrical Conductivity | 14000000 S/m |
Resistivity | 7.1e-8 m Ω |
Superconducting Point | 0.49 |
Ruthenium Heat and Conduction Properties
Thermal Conductivity | 120 W/(m K) |
Thermal Expansion | 0.0000064 /K |
Ruthenium Magnetic Properties
Magnetic Type | Paramagnetic |
Curie Point | - |
Mass Magnetic Susceptibility | 5.42e-9 m3/kg |
Molar Magnetic Susceptibility | 5.48e-10 m3/mol |
Volume Magnetic Susceptibility | 0.000067 |
Optical Properties of Ruthenium
Refractive Index | - |
Acoustic Properties of Ruthenium
Speed of Sound | 5970 m/s |
Ruthenium Thermal Properties - Enthalpies and thermodynamics
Refer to table below for Thermal properties of Ruthenium
Melting Point | 2607 K(2333.85 °C, 4232.930 °F) |
Boiling Point | 4423 K(4149.85 °C, 7501.730 °F) |
Critical Temperature | - |
Superconducting Point | 0.49 |
Enthalpies of Ruthenium
Heat of Fusion | 25.7 kJ/mol |
Heat of Vaporization | 580 kJ/mol |
Heat of Combustion | - |
Ruthenium Isotopes - Nuclear Properties of Ruthenium
Ruthenium has 34 isotopes, with between 87 and 120 nucleons. Ruthenium has 7 stable naturally occuring isotopes.
Isotopes of Ruthenium - Naturally occurring stable Isotopes: 100Ru, 101Ru, 102Ru, 104Ru, 96Ru, 98Ru, 99Ru.
Isotope | Z | N | Isotope Mass | % Abundance | T half | Decay Mode |
---|---|---|---|---|---|---|
87Ru | 44 | 43 | 87 | Synthetic | ||
88Ru | 44 | 44 | 88 | Synthetic | ||
89Ru | 44 | 45 | 89 | Synthetic | ||
90Ru | 44 | 46 | 90 | Synthetic | ||
91Ru | 44 | 47 | 91 | Synthetic | ||
92Ru | 44 | 48 | 92 | Synthetic | ||
93Ru | 44 | 49 | 93 | Synthetic | ||
94Ru | 44 | 50 | 94 | Synthetic | ||
95Ru | 44 | 51 | 95 | Synthetic | ||
96Ru | 44 | 52 | 96 | 5.54% | Stable | N/A |
97Ru | 44 | 53 | 97 | Synthetic | ||
98Ru | 44 | 54 | 98 | 1.87% | Stable | N/A |
99Ru | 44 | 55 | 99 | 12.76% | Stable | N/A |
100Ru | 44 | 56 | 100 | 12.6% | Stable | N/A |
101Ru | 44 | 57 | 101 | 17.06% | Stable | |
102Ru | 44 | 58 | 102 | 31.55% | Stable | N/A |
103Ru | 44 | 59 | 103 | Synthetic | ||
104Ru | 44 | 60 | 104 | 18.62% | Stable | N/A |
105Ru | 44 | 61 | 105 | Synthetic | ||
106Ru | 44 | 62 | 106 | Synthetic | ||
107Ru | 44 | 63 | 107 | Synthetic | ||
108Ru | 44 | 64 | 108 | Synthetic | ||
109Ru | 44 | 65 | 109 | Synthetic | ||
110Ru | 44 | 66 | 110 | Synthetic | ||
111Ru | 44 | 67 | 111 | Synthetic | ||
112Ru | 44 | 68 | 112 | Synthetic | ||
113Ru | 44 | 69 | 113 | Synthetic | ||
114Ru | 44 | 70 | 114 | Synthetic | ||
115Ru | 44 | 71 | 115 | Synthetic | ||
116Ru | 44 | 72 | 116 | Synthetic | ||
117Ru | 44 | 73 | 117 | Synthetic | ||
118Ru | 44 | 74 | 118 | Synthetic | ||
119Ru | 44 | 75 | 119 | Synthetic | ||
120Ru | 44 | 76 | 120 | Synthetic |
Regulatory and Health - Health and Safety Parameters and Guidelines
The United States Department of Transportation (DOT) identifies hazard class of all dangerous elements/goods/commodities either by its class (or division) number or name. The DOT has divided these materials into nine different categories, known as Hazard Classes.
DOT Numbers | 3089 |
DOT Hazard Class | 4.1 |
NFPA 704 is a Standard System for the Identification of the Hazards of Materials for Emergency Response. NFPA is a standard maintained by the US based National Fire Protection Association.
The health (blue), flammability (red), and reactivity (yellow) rating all use a numbering scale ranging from 0 to 4. A value of zero means that the element poses no hazard; a rating of four indicates extreme danger.
NFPA Fire Rating | N/A | N/A |
NFPA Health Rating | N/A | N/A |
NFPA Reactivity Rating | N/A | N/A |
NFPA Hazards | N/A |
Autoignition Point | - |
Flashpoint | - |
Database Search
List of unique identifiers to search the element in various chemical registry databases
Database | Identifier number |
---|---|
CAS Number - Chemical Abstracts Service (CAS) | CAS7440-18-8 |
RTECS Number | - |
CID Number | CID23950 |
Gmelin Number | - |
NSC Number | - |
Compare Ruthenium with other elements
Compare Ruthenium with Group 8, Period 5 and Transition Metal elements of the periodic table.
Compare Ruthenium with all Group 8 elements
Compare Ruthenium with all Period 5 elements
Compare Ruthenium with all Transition Metal elements
Frequently Asked Questions (FAQ)
Find the answers to the most frequently asked questions about Ruthenium