Nitrogen Element Information, Facts, Properties, Trends, Uses, Comparison with other elements
Nitrogen is a chemical element with symbol N and atomic number 7. It is the lightest pnictogen and at room temperature, it is a transparent, odorless diatomic gas. Nitrogen is a common element in the universe, estimated at about seventh in total abundance in the Milky Way and the Solar System.
It belongs to group 15 of the periodic table having trivial name pentels, pnictogens*. You can also download Printable Periodic Table of Elements Flashcards for Nitrogen in a PDF format.
Nitrogen Facts
Read key information and facts about element Nitrogen
Name | Nitrogen |
Atomic Number | 7 |
Atomic Symbol | N |
Atomic Weight | 14.0067 |
Phase | Gas(Diatomic Gas) |
Color | Colorless |
Appearance | colorless gas, liquid or solid |
Classification | Other Nonmetal |
Natural Occurance | Primordial |
Group in Periodic Table | 15 |
Group Name | nitrogen family |
Period in Periodic Table | period 2 |
Block in Periodic Table | p-block |
Electronic Configuration | [He] 2s2 2p3 |
Electronic Shell Structure (Electrons per shell) | 2, 5 |
Melting Point | 63.05 K |
Boiling Point | 77.36 K |
CAS Number | CAS7727-37-9 |
How to Locate Nitrogen on Periodic Table
Periodic table is arranged by atomic number, number of protons in the nucleus which is same as number of electrons. The atomic number increases from left to right. Periodic table starts at top left ( Atomic number 1) and ends at bottom right (atomic number 118). Therefore you can directly look for atomic number 7 to find Nitrogen on periodic table.
Another way to read periodic table and locate an element is by using group number (column) and period number (row). To locate Nitrogen on periodic table look for cross section of group 15 and period 2 in the modern periodic table.
Nitrogen History
The element Nitrogen was discovered by D. Rutherford in year 1772 in United Kingdom. Nitrogen was first isolated by D. Rutherford in 1772. Nitrogen derived its name from the Greek word nitron and '-gen' meaning 'niter-forming'.
Discovered By | D. Rutherford |
Discovery Date | 1772 in United Kingdom |
First Isolation | 1772 |
Isolated by | D. Rutherford |
He discovered Nitrogen while he was studying at theUniversity of Edinburgh. He showed that the air in which animals had breathed, even after removal of the exhaled carbon dioxide, was no longer able to burn a candle. Carl Wilhelm Scheele, Henry Cavendish, and Joseph Priestley also studied the element at about the same time, and Lavoisier named it in 1775-1776.
Nitrogen Uses
78 % of Earth's entire atmosphere is made up of nitrogen. The element is important to the chemical industry as it is a key nutrient in fertilizers and a key component in nitric acid, nylon, and explosive materials. Hydrogen is also reacted with nitrogen to create ammonia.
Nitrogen Presence: Abundance in Nature and Around Us
The table below shows the abundance of Nitrogen in Universe, Sun, Meteorites, Earth's Crust, Oceans and Human Body.
ppb by weight (1ppb =10^-7 %) | ppb by atoms (1ppb =10^-7 %) | |
---|---|---|
Abundance in Universe | 1000000 | 90000 |
Abundance in Sun | 1000000 | 90000 |
Abundance in Meteorites | 1400000 | 1400000 |
Abundance in Earth's Crust | 20000 | 29000 |
Abundance in Oceans | 500 | 220 |
Abundance in Humans | 26000000 | 12000000 |
Crystal Structure of Nitrogen
The solid state structure of Nitrogen is Simple Hexagonal.
The Crystal structure can be described in terms of its unit Cell. The unit Cells repeats itself in three dimensional space to form the structure.
Unit Cell Parameters
The unit cell is represented in terms of its lattice parameters, which are the lengths of the cell edges Lattice Constants (a, b and c)
a | b | c |
---|---|---|
386.1 pm | 386.1 pm | 626.5 pm |
and the angles between them Lattice Angles (alpha, beta and gamma).
alpha | beta | gamma |
---|---|---|
π/2 | π/2 | 2 π/3 |
The positions of the atoms inside the unit cell are described by the set of atomic positions ( xi, yi, zi) measured from a reference lattice point.
The symmetry properties of the crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space are described by the 230 space groups (219 distinct types, or 230 if chiral copies are considered distinct.
Space Group Name | P63/mmc |
Space Group Number | 194 |
Crystal Structure | Simple Hexagonal |
Number of atoms per unit cell |
The number of atoms per unit cell in a simple cubic, face-centered cubic and body-centred cubic are 1,4,2 respectively.
Nitrogen Atomic and Orbital Properties
Nitrogen atoms have 7 electrons and the electronic shell structure is [2, 5] with Atomic Term Symbol (Quantum Numbers) 4S3/2.
Atomic Number | 7 |
Number of Electrons (with no charge) | 7 |
Number of Protons | 7 |
Mass Number | 14 |
Number of Neutrons | 7 |
Shell structure (Electrons per energy level) | 2, 5 |
Electron Configuration | [He] 2s2 2p3 |
Valence Electrons | 2s2 2p3 |
Valence (Valency) | 3 |
Main Oxidation States | -3, 3, 5 |
Oxidation States | -3, -2, -1, 0, 1, 2, 3, 4, 5 |
Atomic Term Symbol (Quantum Numbers) | 4S3/2 |
Bohr Atomic Model of Nitrogen - Electrons per energy level
n | s | p | d | f |
---|
Ground State Electronic Configuration of Nitrogen - neutral Nitrogen atom
Abbreviated electronic configuration of Nitrogen
The ground state abbreviated electronic configuration of Neutral Nitrogen atom is [He] 2s2 2p3. The portion of Nitrogen configuration that is equivalent to the noble gas of the preceding period, is abbreviated as [He]. For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. This is important as it is the Valence electrons 2s2 2p3, electrons in the outermost shell that determine the chemical properties of the element.
Unabbreviated electronic configuration of neutral Nitrogen
Complete ground state electronic configuration for the Nitrogen atom, Unabbreviated electronic configuration
1s2 2s2 2p3
Electrons are filled in atomic orbitals as per the order determined by the Aufbau principle, Pauli Exclusion Principle and Hund’s Rule.
As per the Aufbau principle the electrons will occupy the orbitals having lower energies before occupying higher energy orbitals. According to this principle, electrons are filled in the following order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p…
The Pauli exclusion principle states that a maximum of two electrons, each having opposite spins, can fit in an orbital.
Hund's rule states that every orbital in a given subshell is singly occupied by electrons before a second electron is filled in an orbital.
Atomic Structure of Nitrogen
Nitrogen atomic radius is 56 pm, while it's covalent radius is 75 pm.
Atomic Radius Calculated | 56 pm(0.56 Å) |
Atomic Radius Empirical | 65 pm (0.65 Å) |
Atomic Volume | 22.4131 cm3/mol |
Covalent Radius | 75 pm (0.75 Å) |
Van der Waals Radius | 155 pm |
Neutron Cross Section | 1.91 |
Neutron Mass Absorption | 0.0048 |
Spectral Lines of Nitrogen - Atomic Spectrum of Nitrogen
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from an excess or deficiency of photons in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral lines are the result of interaction between a quantum system and a single photon. A spectral line may be observed either as an emission line or an absorption line.
Spectral lines are highly atom-specific, and can be used to identify the chemical composition of any medium. Several elements, including helium, thallium, and caesium, were discovered by spectroscopic means. They are widely used to determine the physical conditions of stars and other celestial bodies that cannot be analyzed by other means.
Emission spectrum of Nitrogen
Absorption spectrum of Nitrogen
Nitrogen Chemical Properties: Nitrogen Ionization Energies and electron affinity
The electron affinity of Nitrogen is 7 kJ/mol.
Valence | 3 |
Electronegativity | 3.04 |
ElectronAffinity | 7 kJ/mol |
Ionization Energy of Nitrogen
Ionization energy is the amount of energy required to remove an electron from an atom or molecule.in chemistry, this energy is expresed in kilocalories per mole (kcal/mol) or kilojoules per mole (kJ/mol).
Refer to table below for Ionization energies of Nitrogen
Ionization energy number | Enthalpy - kJ/mol |
---|---|
1st | 1402.3 |
2nd | 2856 |
3rd | 4578.1 |
4th | 7475 |
5th | 9444.9 |
6th | 53266.6 |
7th | 64360 |
Nitrogen Physical Properties
Refer to below table for Nitrogen Physical Properties
Density | 0.001251 g/cm3 |
Molar Volume | 22.4131 cm3/mol |
Elastic Properties
Young Modulus | - |
Shear Modulus | - |
Bulk Modulus | - |
Poisson Ratio | - |
Hardness of Nitrogen - Tests to Measure of Hardness of Element
Mohs Hardness | - |
Vickers Hardness | - |
Brinell Hardness | - |
Nitrogen Electrical Properties
Electrical resistivity measures element's electrical resistance or how strongly it resists electric current.The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). While Electrical conductivity is the reciprocal of electrical resistivity. It represents a element's ability to conduct electric current. The SI unit of electrical conductivity is siemens per metre (S/m).
Nitrogen is a -. Refer to table below for the Electrical properties of Nitrogen
Electrical conductors | - |
Electrical Conductivity | - |
Resistivity | - |
Superconducting Point | - |
Nitrogen Heat and Conduction Properties
Thermal Conductivity | 0.02583 W/(m K) |
Thermal Expansion | - |
Nitrogen Magnetic Properties
Magnetic Type | Diamagnetic |
Curie Point | - |
Mass Magnetic Susceptibility | -5.4e-9 m3/kg |
Molar Magnetic Susceptibility | -1.5e-10 m3/mol |
Volume Magnetic Susceptibility | -6.8e-9 |
Optical Properties of Nitrogen
Refractive Index | 1.000298 |
Acoustic Properties of Nitrogen
Speed of Sound | 333.6 m/s |
Nitrogen Thermal Properties - Enthalpies and thermodynamics
Refer to table below for Thermal properties of Nitrogen
Melting Point | 63.05 K(-210.10 °C, -346.180 °F) |
Boiling Point | 77.36 K(-195.79 °C, -320.422 °F) |
Critical Temperature | 126.21 K |
Superconducting Point | - |
Enthalpies of Nitrogen
Heat of Fusion | 0.36 kJ/mol |
Heat of Vaporization | 2.79 kJ/mol |
Heat of Combustion | - |
Nitrogen Isotopes - Nuclear Properties of Nitrogen
Nitrogen has 16 isotopes, with between 10 and 25 nucleons. Nitrogen has 2 stable naturally occuring isotopes.
Isotopes of Nitrogen - Naturally occurring stable Isotopes: 14N, 15N.
Isotope | Z | N | Isotope Mass | % Abundance | T half | Decay Mode |
---|---|---|---|---|---|---|
10N | 7 | 3 | 10 | Synthetic | ||
11N | 7 | 4 | 11 | Synthetic | ||
12N | 7 | 5 | 12 | Synthetic | ||
13N | 7 | 6 | 13 | Synthetic | ||
14N | 7 | 7 | 14 | 99.632% | Stable | |
15N | 7 | 8 | 15 | 0.368% | Stable | N/A |
16N | 7 | 9 | 16 | Synthetic | ||
17N | 7 | 10 | 17 | Synthetic | ||
18N | 7 | 11 | 18 | Synthetic | ||
19N | 7 | 12 | 19 | Synthetic | ||
20N | 7 | 13 | 20 | Synthetic | ||
21N | 7 | 14 | 21 | Synthetic | ||
22N | 7 | 15 | 22 | Synthetic | ||
23N | 7 | 16 | 23 | Synthetic | ||
24N | 7 | 17 | 24 | Synthetic | ||
25N | 7 | 18 | 25 | Synthetic |
Regulatory and Health - Health and Safety Parameters and Guidelines
The United States Department of Transportation (DOT) identifies hazard class of all dangerous elements/goods/commodities either by its class (or division) number or name. The DOT has divided these materials into nine different categories, known as Hazard Classes.
DOT Numbers | 1977 |
DOT Hazard Class | 2.2 |
NFPA 704 is a Standard System for the Identification of the Hazards of Materials for Emergency Response. NFPA is a standard maintained by the US based National Fire Protection Association.
The health (blue), flammability (red), and reactivity (yellow) rating all use a numbering scale ranging from 0 to 4. A value of zero means that the element poses no hazard; a rating of four indicates extreme danger.
NFPA Fire Rating | 0 | Will not burn |
NFPA Health Rating | 3 | Flash Points below 37.8°C (100°F) |
NFPA Reactivity Rating | 0 | Will not burn |
NFPA Hazards |
Autoignition Point | - |
Flashpoint | - |
Database Search
List of unique identifiers to search the element in various chemical registry databases
Database | Identifier number |
---|---|
CAS Number - Chemical Abstracts Service (CAS) | CAS7727-37-9 |
RTECS Number | RTECSQW9700000 |
CID Number | CID947 |
Gmelin Number | - |
NSC Number | - |
Compare Nitrogen with other elements
Compare Nitrogen with Group 15, Period 2 and Other Nonmetal elements of the periodic table.
Compare Nitrogen with all Group 15 elements
Compare Nitrogen with all Period 2 elements
Compare Nitrogen with all Other Nonmetal elements
Frequently Asked Questions (FAQ)
Find the answers to the most frequently asked questions about Nitrogen