Niobium Element Information, Facts, Properties, Trends, Uses, Comparison with other elements
Niobium, formerly columbium, is a chemical element with symbol Nb (formerly Cb) and atomic number 41. It is a soft, grey, ductile Transition Metal, which is often found in the pyrochlore mineral, the main commercial source for niobium, and columbite. The name comes from Greek mythology:Niobe, daughter of Tantalus since it is so similar to tantalum.
It belongs to group 5 of the periodic table having trivial name null. You can also download Printable Periodic Table of Elements Flashcards for Niobium in a PDF format.
Niobium Facts
Read key information and facts about element Niobium
Name | Niobium |
Atomic Number | 41 |
Atomic Symbol | Nb |
Atomic Weight | 92.90638 |
Phase | Solid |
Color | Gray |
Appearance | gray metallic, bluish when oxidized |
Classification | Transition Metal |
Natural Occurance | Primordial |
Group in Periodic Table | 5 |
Group Name | vanadium family |
Period in Periodic Table | period 5 |
Block in Periodic Table | d-block |
Electronic Configuration | [Kr] 4d4 5s1 |
Electronic Shell Structure (Electrons per shell) | 2, 8, 18, 12, 1 |
Melting Point | 2750 K |
Boiling Point | 5017 K |
CAS Number | CAS7440-03-1 |
How to Locate Niobium on Periodic Table
Periodic table is arranged by atomic number, number of protons in the nucleus which is same as number of electrons. The atomic number increases from left to right. Periodic table starts at top left ( Atomic number 1) and ends at bottom right (atomic number 118). Therefore you can directly look for atomic number 41 to find Niobium on periodic table.
Another way to read periodic table and locate an element is by using group number (column) and period number (row). To locate Niobium on periodic table look for cross section of group 5 and period 5 in the modern periodic table.
Niobium History
The element Niobium was discovered by C. Hatchett in year 1801 in United Kingdom. Niobium was first isolated by W. Blomstrand in 1864. Niobium derived its name from Niobe, daughter of king Tantalus from Greek mythology.
Discovered By | C. Hatchett |
Discovery Date | 1801 in United Kingdom |
First Isolation | 1864 |
Isolated by | W. Blomstrand |
Hatchett found the element incolumbiteore and named it columbium. Heinrich Rose proved in 1844 that the element is distinct from tantalum, and renamed it niobium which was officially accepted in 1949.
Niobium Uses
Niobium is used in stainless steel alloys. Alloys created with Niobium are very strong and are usually used in pipelines and jet engines.
Niobium Presence: Abundance in Nature and Around Us
The table below shows the abundance of Niobium in Universe, Sun, Meteorites, Earth's Crust, Oceans and Human Body.
ppb by weight (1ppb =10^-7 %) | ppb by atoms (1ppb =10^-7 %) | |
---|---|---|
Abundance in Universe | 2 | 0.02 |
Abundance in Sun | 4 | 0.05 |
Abundance in Meteorites | 190 | 30 |
Abundance in Earth's Crust | 17000 | 3700 |
Abundance in Oceans | 0.001 | 0.000067 |
Abundance in Humans | - | - |
Crystal Structure of Niobium
The solid state structure of Niobium is Body Centered Cubic.
The Crystal structure can be described in terms of its unit Cell. The unit Cells repeats itself in three dimensional space to form the structure.
Unit Cell Parameters
The unit cell is represented in terms of its lattice parameters, which are the lengths of the cell edges Lattice Constants (a, b and c)
a | b | c |
---|---|---|
330.04 pm | 330.04 pm | 330.04 pm |
and the angles between them Lattice Angles (alpha, beta and gamma).
alpha | beta | gamma |
---|---|---|
π/2 | π/2 | π/2 |
The positions of the atoms inside the unit cell are described by the set of atomic positions ( xi, yi, zi) measured from a reference lattice point.
The symmetry properties of the crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space are described by the 230 space groups (219 distinct types, or 230 if chiral copies are considered distinct.
Space Group Name | Im_ 3m |
Space Group Number | 229 |
Crystal Structure | Body Centered Cubic |
Number of atoms per unit cell | 2 |
The number of atoms per unit cell in a simple cubic, face-centered cubic and body-centred cubic are 1,4,2 respectively.
Niobium Atomic and Orbital Properties
Niobium atoms have 41 electrons and the electronic shell structure is [2, 8, 18, 12, 1] with Atomic Term Symbol (Quantum Numbers) 6D1/2.
Atomic Number | 41 |
Number of Electrons (with no charge) | 41 |
Number of Protons | 41 |
Mass Number | 93 |
Number of Neutrons | 52 |
Shell structure (Electrons per energy level) | 2, 8, 18, 12, 1 |
Electron Configuration | [Kr] 4d4 5s1 |
Valence Electrons | 4d4 5s1 |
Valence (Valency) | 5 |
Main Oxidation States | 5 |
Oxidation States | -3, -1, 0, 1, 2, 3, 4, 5 |
Atomic Term Symbol (Quantum Numbers) | 6D1/2 |
Bohr Atomic Model of Niobium - Electrons per energy level
n | s | p | d | f |
---|
Ground State Electronic Configuration of Niobium - neutral Niobium atom
Abbreviated electronic configuration of Niobium
The ground state abbreviated electronic configuration of Neutral Niobium atom is [Kr] 4d4 5s1. The portion of Niobium configuration that is equivalent to the noble gas of the preceding period, is abbreviated as [Kr]. For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. This is important as it is the Valence electrons 4d4 5s1, electrons in the outermost shell that determine the chemical properties of the element.
Unabbreviated electronic configuration of neutral Niobium
Complete ground state electronic configuration for the Niobium atom, Unabbreviated electronic configuration
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d4 5s1
Electrons are filled in atomic orbitals as per the order determined by the Aufbau principle, Pauli Exclusion Principle and Hund’s Rule.
As per the Aufbau principle the electrons will occupy the orbitals having lower energies before occupying higher energy orbitals. According to this principle, electrons are filled in the following order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p…
The Pauli exclusion principle states that a maximum of two electrons, each having opposite spins, can fit in an orbital.
Hund's rule states that every orbital in a given subshell is singly occupied by electrons before a second electron is filled in an orbital.
Atomic Structure of Niobium
Niobium atomic radius is 198 pm, while it's covalent radius is 137 pm.
Atomic Radius Calculated | 198 pm(1.98 Å) |
Atomic Radius Empirical | 145 pm (1.45 Å) |
Atomic Volume | 10.841 cm3/mol |
Covalent Radius | 137 pm (1.37 Å) |
Van der Waals Radius | - |
Neutron Cross Section | 1.15 |
Neutron Mass Absorption | 0.0004 |
Spectral Lines of Niobium - Atomic Spectrum of Niobium
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from an excess or deficiency of photons in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral lines are the result of interaction between a quantum system and a single photon. A spectral line may be observed either as an emission line or an absorption line.
Spectral lines are highly atom-specific, and can be used to identify the chemical composition of any medium. Several elements, including helium, thallium, and caesium, were discovered by spectroscopic means. They are widely used to determine the physical conditions of stars and other celestial bodies that cannot be analyzed by other means.
Emission spectrum of Niobium
Absorption spectrum of Niobium
Niobium Chemical Properties: Niobium Ionization Energies and electron affinity
The electron affinity of Niobium is 86.1 kJ/mol.
Valence | 5 |
Electronegativity | 1.6 |
ElectronAffinity | 86.1 kJ/mol |
Ionization Energy of Niobium
Ionization energy is the amount of energy required to remove an electron from an atom or molecule.in chemistry, this energy is expresed in kilocalories per mole (kcal/mol) or kilojoules per mole (kJ/mol).
Refer to table below for Ionization energies of Niobium
Ionization energy number | Enthalpy - kJ/mol |
---|---|
1st | 652.1 |
2nd | 1380 |
3rd | 2416 |
4th | 3700 |
5th | 4877 |
6th | 9847 |
7th | 12100 |
Niobium Physical Properties
Refer to below table for Niobium Physical Properties
Density | 8.57 g/cm3 |
Molar Volume | 10.841 cm3/mol |
Elastic Properties
Young Modulus | 105 |
Shear Modulus | 38 GPa |
Bulk Modulus | 170 GPa |
Poisson Ratio | 0.4 |
Hardness of Niobium - Tests to Measure of Hardness of Element
Mohs Hardness | 6 MPa |
Vickers Hardness | 1320 MPa |
Brinell Hardness | 736 MPa |
Niobium Electrical Properties
Electrical resistivity measures element's electrical resistance or how strongly it resists electric current.The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). While Electrical conductivity is the reciprocal of electrical resistivity. It represents a element's ability to conduct electric current. The SI unit of electrical conductivity is siemens per metre (S/m).
Niobium is a conductor of electricity. Refer to table below for the Electrical properties of Niobium
Electrical conductors | Conductor |
Electrical Conductivity | 6700000 S/m |
Resistivity | 1.5e-7 m Ω |
Superconducting Point | 9.25 |
Niobium Heat and Conduction Properties
Thermal Conductivity | 54 W/(m K) |
Thermal Expansion | 0.00000729 /K |
Niobium Magnetic Properties
Magnetic Type | Paramagnetic |
Curie Point | - |
Mass Magnetic Susceptibility | 2.76e-8 m3/kg |
Molar Magnetic Susceptibility | 2.56e-9 m3/mol |
Volume Magnetic Susceptibility | 0.000237 |
Optical Properties of Niobium
Refractive Index | - |
Acoustic Properties of Niobium
Speed of Sound | 3480 m/s |
Niobium Thermal Properties - Enthalpies and thermodynamics
Refer to table below for Thermal properties of Niobium
Melting Point | 2750 K(2476.85 °C, 4490.330 °F) |
Boiling Point | 5017 K(4743.85 °C, 8570.930 °F) |
Critical Temperature | - |
Superconducting Point | 9.25 |
Enthalpies of Niobium
Heat of Fusion | 26.8 kJ/mol |
Heat of Vaporization | 690 kJ/mol |
Heat of Combustion | - |
Niobium Isotopes - Nuclear Properties of Niobium
Niobium has 33 isotopes, with between 81 and 113 nucleons. Niobium has 1 stable naturally occuring isotopes.
Isotopes of Niobium - Naturally occurring stable Isotopes: 93Nb.
Isotope | Z | N | Isotope Mass | % Abundance | T half | Decay Mode |
---|---|---|---|---|---|---|
81Nb | 41 | 40 | 81 | Synthetic | ||
82Nb | 41 | 41 | 82 | Synthetic | ||
83Nb | 41 | 42 | 83 | Synthetic | ||
84Nb | 41 | 43 | 84 | Synthetic | ||
85Nb | 41 | 44 | 85 | Synthetic | ||
86Nb | 41 | 45 | 86 | Synthetic | ||
87Nb | 41 | 46 | 87 | Synthetic | ||
88Nb | 41 | 47 | 88 | Synthetic | ||
89Nb | 41 | 48 | 89 | Synthetic | ||
90Nb | 41 | 49 | 90 | Synthetic | ||
91Nb | 41 | 50 | 91 | Synthetic | ||
92Nb | 41 | 51 | 92 | Synthetic | ||
93Nb | 41 | 52 | 93 | 100% | Stable | |
94Nb | 41 | 53 | 94 | Synthetic | ||
95Nb | 41 | 54 | 95 | Synthetic | ||
96Nb | 41 | 55 | 96 | Synthetic | ||
97Nb | 41 | 56 | 97 | Synthetic | ||
98Nb | 41 | 57 | 98 | Synthetic | ||
99Nb | 41 | 58 | 99 | Synthetic | ||
100Nb | 41 | 59 | 100 | Synthetic | ||
101Nb | 41 | 60 | 101 | Synthetic | ||
102Nb | 41 | 61 | 102 | Synthetic | ||
103Nb | 41 | 62 | 103 | Synthetic | ||
104Nb | 41 | 63 | 104 | Synthetic | ||
105Nb | 41 | 64 | 105 | Synthetic | ||
106Nb | 41 | 65 | 106 | Synthetic | ||
107Nb | 41 | 66 | 107 | Synthetic | ||
108Nb | 41 | 67 | 108 | Synthetic | ||
109Nb | 41 | 68 | 109 | Synthetic | ||
110Nb | 41 | 69 | 110 | Synthetic | ||
111Nb | 41 | 70 | 111 | Synthetic | ||
112Nb | 41 | 71 | 112 | Synthetic | ||
113Nb | 41 | 72 | 113 | Synthetic |
Regulatory and Health - Health and Safety Parameters and Guidelines
The United States Department of Transportation (DOT) identifies hazard class of all dangerous elements/goods/commodities either by its class (or division) number or name. The DOT has divided these materials into nine different categories, known as Hazard Classes.
NFPA 704 is a Standard System for the Identification of the Hazards of Materials for Emergency Response. NFPA is a standard maintained by the US based National Fire Protection Association.
The health (blue), flammability (red), and reactivity (yellow) rating all use a numbering scale ranging from 0 to 4. A value of zero means that the element poses no hazard; a rating of four indicates extreme danger.
NFPA Fire Rating | N/A | N/A |
NFPA Health Rating | N/A | N/A |
NFPA Reactivity Rating | N/A | N/A |
NFPA Hazards | N/A |
Autoignition Point | - |
Flashpoint | - |
Database Search
List of unique identifiers to search the element in various chemical registry databases
Database | Identifier number |
---|---|
CAS Number - Chemical Abstracts Service (CAS) | CAS7440-03-1 |
RTECS Number | RTECSQT9900000 |
CID Number | CID23936 |
Gmelin Number | - |
NSC Number | - |
Compare Niobium with other elements
Compare Niobium with Group 5, Period 5 and Transition Metal elements of the periodic table.
Compare Niobium with all Group 5 elements
Compare Niobium with all Period 5 elements
Compare Niobium with all Transition Metal elements
Frequently Asked Questions (FAQ)
Find the answers to the most frequently asked questions about Niobium